Let $R(v_{\bullet}, w_{\bullet})$ be some $P$-time computable relation between two binary strings $v_{\bullet}$ and $w_{\bullet}$. $NP$ problems are problems of the form: Given $v_{\bullet}$, determine whether there exists an $w_{\bullet}$ so that $R(v_{\bullet}, w_{\bullet})$. The $\# P$ problems are problems of the form: Given $v_{\bullet}$, count the number of $w_{\bullet}$ satisfying $R(v_{\bullet}, w_{\bullet})$.
There are certainly examples of $R$ from which the counting problem is hard but the existence problem is not: Determining whether a graph has a perfect matching is in $P$, but counting the perfect matchings is $\# P$-complete.
What are examples of relations $R$ for the existence problem is $NP$-complete but the counting problem is, subject to reasonable conjectures, not $\# P$-complete?