For any arbitrary NP complete language is there always a polytime superset the complement of which is also infinite?
A trivial version which does not stipulate the superset to have infinite complement has been asked at https://cs.stackexchange.com/q/50123/42961
For purposes of this question, you can assume that $P \ne NP$. As Vor explained, if $P = NP$ then the answer is "No". (If $P = NP$, then $X = \{x \mid x \in \mathbb{N^+} \land x > 1\}$ is NP-complete. Clearly there is no superset of $X$ which is infinite and has an infinite complement, as the complement of $X$ has only a single element.) Thus we can focus on the case $P \ne NP$.