For a given Büchi automaton $\mathcal A = (A, Q, \delta, q_0, F)$ we define a congruence on $A^{\ast}$ by $$ \begin{array}{llll} u \sim_{\mathcal A} v & :\Leftrightarrow & \mbox{for all }s,s' \in Q \mbox{ we have a path} \\ & & \mbox{from $s$ to $s'$ labeled by $v$ iff we have} \\ & & \mbox{such a path labeled by $w$ and} \\ & & \mbox{we have such a path which passes through a state from $F$} \\ & & \mbox{labeled by $v$ iff we have such a path labeled by $w$}. \end{array} $$ for $u, v \in A^{\ast}$. Now setting $W_{ss'} := \{ w \in A^{\ast} \mid \mbox{there is a path labeled $w$ from $s$ to $s'$}\}$ and $W_{ss'}^{F} := \{ w \in A^{\ast} \mid \mbox{there is a path labeled $w$ from $s$ to $s'$ going through a state in $F$}\}$ we have $$ [w]_{\sim_{\mathcal A}} = \bigcap_{\substack{s,s'\in Q \\ w \in W_{ss'}}} W_{ss'} \cap \bigcap_{\substack{s,s' \in Q \\ w \in A^{\ast} \setminus W_{ss'}}} A^{\ast}\setminus W_{ss'} \bigcap_{\substack{s,s'\in Q \\ w \in W_{ss'}^F}} W_{ss'}^F \cap \bigcap_{\substack{s,s' \in Q \\ w \in A^{\ast} \setminus W_{ss'}^F}} A^{\ast}\setminus W_{ss'}^F. $$ This equivalence is defined here and also in the the chapter Automata on infinite objects by Wolfgang Thomas in the Handbook of Theoretical Computer Science, Volume II. In this book it is said
Let us consider the complexity of the complementation process and the equivalence test. Given a Büchi automaton with $n$ states, there are $n^2$ different pairs $(s,s')$ and hence $O(2^{2n^2})$ different $\sim_{\mathcal A}$-classes. This leads to size bound of $O(2^{4n^2})$ states for the complement automaton.
As in the above formula, for each set $W_{ss'}$ (and $W_{ss'}^F$) we can decide wether it occurs in the intersection (and hence determines if one complement $A^{\ast}\setminus W_{ss'}$ and $A^{\ast} \setminus W_{ss'}^F$ occurs) we have $2^{n^2}\cdot 2^{n^2}$ options (different then $|Q^{2^{2Q}}|$ which would be given by the identification of the classes with functions $f : Q \to 2^Q \times 2^Q$ in the wikipedia article).
But why does this lead to a size bound of $O(2^{4n^2})$ for the complement automaton?
I do not see how to get a complement automaton such that this size bound could be easily seen?