According to this Wikipage series-parallel graphs are characterized like this:
2-connected series-parallel graphs are characterized by having no subgraph homeomorphic to $K_4$.
I couldn't find a similar characterization for series-parallel directed acyclic graphs (DAGs), however I think that the prohibited subgraph in this case can be a little simpler ($K_4$ minus one edge plus specific orientation):
Is it correct? Is it proven anywhere?